High valuable wax from multilayer film packaging wastes using solid catalyst via pyrolysis process

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Author listPisitpong Intarapong, Jitima Preechawong, Manit Nithitanakul

PublisherElsevier

Publication year2024

JournalWaste Management (0956-053X)

Volume number186

Start page205

End page213

Number of pages9

ISSN0956-053X

eISSN1879-2456

LanguagesEnglish-United States (EN-US)


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Abstract

Multilayer film packaging (MLP) waste was decomposed completely at 500 °C. Catalysts were employed to convert residue polymer to waxes via pyrolysis at 500 °C. The activities achieved from using mordenite (Si/Al = 10), H-ZSM-5 (Si/Al = 25), MCM-41, and Al-MCM-41 (Si/Al ratio of 25, 50, and 75) catalysts were studied. The yield and property of the wax were improved with the use of the catalysis with various acidity and porous structure. The low yield of the waxes, when using mordenite and H-ZSM-5 catalysts, was caused by the microporous structure and strong acidic properties of the catalysts resulting in larger amount of gas production. The MCM-41 catalyst modified with various aluminum content raised the wax yield to 60 %. Al-MCM-41(50) produced the largest amount of wax when compared to Al-MCM-41(25), Al-MCM-41(75), and MCM-41. The mild acidity and mesoporous structure of Al-MCM-41(50) significantly enhanced the paraffins structure of the obtained waxes over other structures, while lower Si/Al ratios favored the conversion of paraffins toward olefin structure. The pyrolysis of MLP with Al-MCM-41(50) produced paraffins and olefins with the middle carbon ranging (C11-20) which were similar quality to pharmaceutical grade of petroleum wax. The spent catalysts of Al-MCM-41 series gradually decreased in wax yield and paraffins composition during the sequential MLP pyrolysis; however, the activity of catalysts was recovered after calcination of the spent catalysts. Furthermore, the viscosity of waxes obtained from Al-MCM-41(50) was 2384 Pa.s at 25 °C similar to the viscosity from commercial petroleum jelly base of 2333 Pa.s.


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Last updated on 2024-02-07 at 00:00