Photocatalytic performance of electrospun CNT/TiO2 nanofibers in a simulated air purifier under visible light irradiation

บทความในวารสาร

ผู้เขียน/บรรณาธิการ

กลุ่มสาขาการวิจัยเชิงกลยุทธ์

ไม่พบข้อมูลที่เกี่ยวข้อง

รายละเอียดสำหรับงานพิมพ์

รายชื่อผู้แต่ง: Wongaree M., Chiarakorn S., Chuangchote S., Sagawa T.

ผู้เผยแพร่: Springer

ปีที่เผยแพร่ (ค.ศ.): 2016

วารสาร: Environmental Science and Pollution Research (0944-1344)

Volume number: 23

Issue number: 21

หน้าแรก: 21395

หน้าสุดท้าย: 21406

จำนวนหน้า: 12

นอก: 0944-1344

eISSN: 1614-7499

URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84981234102&doi=10.1007%2fs11356-016-7348-z&partnerID=40&md5=755c21c637765aaacd290e7b8b890a71

ภาษา: English-Great Britain (EN-GB)

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บทคัดย่อ

The photocatalytic treatment of gaseous benzene under visible light irradiation was developed using electrospun carbon nanotube/titanium dioxide (CNT/TiO2) nanofibers as visible light active photocatalysts. The CNT/TiO2 nanofibers were fabricated by electrospinning CNT/poly(vinyl pyrrolidone) (PVP) solution followed by the removal of PVP by calcination at 450 °C. The molar ratio of CNT/TiO2 was fixed at 0.05:1 by weight, and the quantity of CNT/TiO2 loaded in PVP solution varied between 30 and 60 % wt. CNT/TiO2 nanofibers have high specific surface area (116 m2/g), significantly higher than that of TiO2 nanofibers (44 m2/g). The photocatalytic performance of the CNT/TiO2 nanofibers was investigated by decolorization of 1 × 10−5 M methylene blue (MB) dye (in water solution) and degradation of 100 ppm gaseous benzene under visible light irradiation. The 50-CNT/TiO2 nanofibers (calcined CNT/TiO2 nanofibers fabricated from a spinning solution of 50 % wt CNT/TiO2 based on PVP) had higher MB degradation efficiency (58 %) than did other CNT/TiO2 nanofibers and pristine TiO2 nanofibers (15 %) under visible light irradiation. The photocatalytic degradation of gaseous benzene under visible light irradiation on filters made of 50-CNT/TiO2 nanofibers was carried out in a simulated air purifier system. Similar to MB results, the degradation efficiency of gaseous benzene by 50-CNT/TiO2 nanofibers (52 %) was higher than by other CNT/TiO2 nanofibers and pristine TiO2 nanofibers (18 %). The synergistic effects of the larger surface area and lower band gap energy of CNT/TiO2 nanofibers were presented as strong adsorption ability and greater visible light adsorption. The CNT/TiO2 nanofiber prepared in this study has potential for use in air purifiers to improve air treatment efficiency with less energy. © 2016, Springer-Verlag Berlin Heidelberg.

คำสำคัญ

Carbon nanotube/titanium dioxide nanofibers, Poly(vinyl pyrrolidone), Simulated air purifier, Visible light irradiation