Influence of the viscosity ratio of polyacrylonitrile/poly(methyl methacrylate) solutions on core-shell fibers prepared by coaxial electrospinning
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Author list: Kaerkitcha N., Chuangchote S., Hachiya K., Sagawa T.
Publisher: Springer Nature [academic journals on nature.com]
Publication year: 2017
Journal: Polymer Journal (0032-3896)
Volume number: 49
Issue number: 6
Start page: 497
End page: 502
Number of pages: 6
ISSN: 0032-3896
eISSN: 1349-0540
Languages: English-Great Britain (EN-GB)
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Abstract
The range of viscosity ratios suitable for the fabrication of core-shell fibers was studied using a mixture of poly(methyl methacrylate) and polyacrylonitrile as a test system. The effect of the viscosity ratio of the outer/inner solutions on the morphology of the obtained core-shell fibers was studied by altering the concentrations of the two polymer solutions. The different viscosity ratios of the outer/inner solutions affected the uniform core-shell structure formation, overall diameter and wall thickness of the obtained fibers, which was confirmed by scanning electron microscopic and transmission electron microscopic observations. It was found that a viscosity ratio of the outer/inner solutions ranging from 1.22 to 2.82 resulted in uniform core-shell morphologies of the resultant electrospun fibers. ฉ 2017 The Society of Polymer Science, Japan (SPSJ) All rights reserved.
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