Wood, silver-substituted zeolite and triclosan as biodegradation controllers and antibacterial agents for poly(lactic acid) (PLA) and PLA composites
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Publication Details
Author list: Prapruddivongs C., Sombatsompop N.
Publisher: SAGE Publications
Publication year: 2017
Journal: Journal of Thermoplastic Composite Materials (0892-7057)
Volume number: 30
Issue number: 5
Start page: 583
End page: 598
Number of pages: 16
ISSN: 0892-7057
eISSN: 1530-7980
Languages: English-Great Britain (EN-GB)
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Abstract
Poly(lactic acid) (PLA) and wood flour/PLA composites were prepared and blended with two antimicrobial agents, triclosan and silver-substituted zeolite (Zeomic), using a twin-screw extruder. The mechanical and thermal properties, antimicrobial activity, and biodegradation performance were investigated. The addition of wood and Zeomic was found to increase the Young's modulus of the composites, whereas the tensile strength, elongation at break, and impact strength dropped. However, the mechanical properties of PLA and wood/PLA loaded with triclosan did not show any definite trends. Differential scanning calorimetry data indicated that the glass transition temperature value of neat PLA was 63ฐC, whereas those of wood/PLA composites were lower. When wood and Zeomic were incorporated, PLA exhibited double melting peaks. Triclosan (1.0 and 1.5 wt%) demonstrated antibacterial activity against Staphylococcus aureus, as determined by plate count agar technique, whereas Zeomic did not. Biodegradation tests of neat PLA and wood/PLA composites showed that after a 60-day incubation period, the biodegradation rate of wood/PLA was higher than that of PLA. PLA and wood/PLA-containing Zeomic were found to degrade more quickly, suggesting that wood and Zeomic acted as biodegradation promoters. On the other hand, triclosan could be considered a biodegradation retarder since no biodegradation was observed for any triclosan-loaded samples during the initial 20 days of incubation, while neat PLA and wood/PLA composites began to degrade within the first few days. ฉ SAGE Publications.
Keywords
Antibacterial properties