Facile synthesis of highly conductive PEDOT:PSS: Via surfactant templates

Journal article

Authors/Editors

NOPHAWAN PARADEE

Strategic Research Themes

No matching items found.

Publication Details

Author list: Sakunpongpitiporn P., Phasuksom K., Paradee N., Sirivat A.

Publisher: Springer

Publication year: 2019

Journal: Journal of Materials Science (0022-2461)

Volume number: 9

Issue number: 11

Start page: 6363

End page: 6378

Number of pages: 16

ISSN: 0022-2461

eISSN: 1573-4803

URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062672669&doi=10.1007%2fs10853-019-03480-1&partnerID=40&md5=4e07dbb7eec3896292a080a3c41db654

Languages: English-Great Britain (EN-GB)

View in Web of Science | View on publisher site | View citing articles in Web of Science

Abstract

Harvesting waste energy through thermoelectric has widely gained attention to aid green energy production. Current efforts are to take advantages of nanomaterials and nanosystems because of dramatic improvements in the performance. However, its cost-effectiveness in generating a 3D configuration for a large-area use is hindered by high production cost. To overcome the present challenges, we propose a flexible and lightweight thermoelectric developed on a melamine foam using a simple dip-dry technique to self-assemble conductive nanofilms in the scaffold. Different amounts of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) conductive nanofilms were variedly fabricated in the foam due to altered amounts of sodium dodecyl sulfate (SDS) surfactant from 0 to 5 wt%. Together with experimental results, a theoretical model was constructed to predict thermal and electrical conductivities, indicating the strong influence of SDS to the electrical conductivity. As a result, the highest nanofilm formation in the foam structure is achieved by adding SDS at 3 wt%. The figure of merit (ZT) of thermoelectric foam is about 0.006–0.007. Our first device was also demonstrated with output voltage of 1.1 mV (ΔT = 40 K). The present study could provide the design and optimization of a hybrid thermoelectric that can act as a simultaneous thermal insulator and power generator. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

Keywords