Preparation and Characterization of Iron Oxide Decorated Graphene Nanoplatelets for Use as Barrier Enhancing Fillers in Polyurethane Based Solar Cell Encapsulant
Conference proceedings article
ผู้เขียน/บรรณาธิการ
กลุ่มสาขาการวิจัยเชิงกลยุทธ์
รายละเอียดสำหรับงานพิมพ์
รายชื่อผู้แต่ง: Yuwawech K., Wootthikanokkhan J., Tanpichai S.
ผู้เผยแพร่: Elsevier
ปีที่เผยแพร่ (ค.ศ.): 2020
Volume number: 23
หน้าแรก: 703
หน้าสุดท้าย: 711
จำนวนหน้า: 9
นอก: 2214-7853
eISSN: 2214-7853
ภาษา: English-Great Britain (EN-GB)
บทคัดย่อ
This work has concerned the development of iron oxide (Fe3O 4)/graphene nanoplatelets (GNPs) for use as barrier enhancing filler in polyurethane based encapsulating materials. The aim of this work is to investigate the effects of GNPs types and the concentration of Fe3O4 on orientation the functionalized GNPs in the PU composites under magnetic field. It was hypothesized that, by properly controlling the orientation of GNPs in the polymer matrix, the greater barrier properties of the composite encapsulant can be expected. Experimentally, Fe3O4 nanoparticles were firstly prepared by treating ferric chloride hexahydrate (FeCl3.6H2O) with hydrazine (N2H4). After that, the product (Fe3O4) was introduced into GNPs. The ratio of the Fe3O4 nanoparticles to GNPs was varied between 0.1 and 1. Superparamagnetic behavior of the composite was observed when the weight ratio of Fe3O 4 to GNPs was greater than 0.3/1. Consequently, this ratio was used for the preparation of polyurethane/GNPs nanocomposite. Finally, the feasibility of applying the film reinforced with PU/Fe3O4 decorated GNPs as an encapsulating material for a flexible organic photovoltaic cell was explored. Performance and durability of the various devices were measured and compared. © 2019 Elsevier Ltd.
คำสำคัญ
Fe3O4-GNPs, Graphene nanoplatelets (GNPs), Superparamagnetic
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